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New Hybrid Technique to Create Corrosion-resistant Nickel Coatings

Published on 2020-02-25. Edited By : SpecialChem

TAGS:  Industrial Coatings     Automotive Coatings    

Purdue University innovators have created a hybrid technique to form a new form of nickel that may help the future production of lifesaving medical devices, high-tech devices and vehicles with strong corrosion-resistant protection.


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Manufacturing of Nanotwinned Nickel Coatings


The hybrid technique enables the manufacturing of nanotwinned nickel coatings with high-density twin boundaries and few conventional grain boundaries, which leads to superb mechanical, electrical properties and high corrosive resistance, suggesting good durability for applications at extreme environments.

Corrosion-resistant Coatings for Automobiles


Potential applications for this Purdue technology include the semiconductor and automotive industries, which need metallic materials with advanced electric and mechanical properties for manufacturing. The nanotwinned nickel can be applied as corrosion-resistant coatings for the automobile, gas and oil industries.

The Purdue technique involves a process where high-yield electrodeposition is applied on certain conductive substrates.

One of the biggest challenges for manufacturers with nickel is dealing with the places within the metals where the crystalline grains intersect, which are known as the boundary areas. These conventional grain boundaries can strengthen metals for high-strength demand.

However, they often act as stress concentrators and they are vulnerable sites for electron scattering and corrosion attack. As a result, conventional boundaries often decrease ductility, corrosion resistance and electrical conductivity.

Another specific type of boundary, much less common in metals such as nickel due to its high-stacking fault energy, is called a twin boundary. The unique nickel in a single-crystal-like form has high-density ultrafine twin structure but few conventional grain boundaries.

Produce Stronger, Corrosion-resistant Nickel


This particular nickel will promote strength, ductility and improve corrosion resistance. Those properties are important for manufacturers across several industries – including automotive, gas, oil and micro-electro-mechanical devices.

The solution of the researchers at Purdue is to use a single crystal substrate as a growth template with a designed electrochemical recipe to promote the formation of twin boundaries and inhibit the formation of conventional grain boundaries. The high-density twin boundaries contribute a high mechanical strength exceeding 2 GPa, a low corrosion current density of 6.91 × 10−8 A cm−2, and high polarization resistance of 516 kΩ.

The new nickel hybrid technique can be potentially integrated to the micro-electro-mechanical system industry after careful engineering designs. MEMS medical devices are used in critical care departments and other hospital areas to monitor patients.

The relevant pressure sensors and other functional small-scale components in MEMS require the use of materials with superior mechanical and structural stability and chemical reliability.


Source: Purdue University
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